Would i be able to overclock either my GPU or CPU with only a 500W Moduclar antec PSU or would it be better to buy a new PSU first?
I am currently running: ASrock 970 Extreme3 AMD FX-4100 EVGA 650ti 1GB Antec 500W Modular OCZ 60GB Vertex 2 Samsung 1TB (not sure what model but its at 7200rpm) WiFi PCI card
You'll be fine. As long as you don't add too much on the system afterwards. But as usual, it's always better to have a surplus of wattage to work with, do I'd recommend getting a new on anyways.