Issue with Razer Synapse 2.0 and 360 controller

Just picked up a Razer Deathadder 2013 a little while back. Question I have is there a way to have Synapse 2.0 switch you back to Defalt profile for windows automaticly. Or do you have to do this on your own every time.

And what is a good free mapper for the 360 controller. Thanks