Intel Optane 905P Series 960GB (SSDPE21D960GAM3) vs Samsung 2TB 980 Pro as boot drive on windows 10?

Optane goes here.

You are right on the money. When I benchmarked the 905P (380GB M.2 model) using AIDA64, putting the device on chipset-connected PCIe slots decreased random 4K read performance by about 8%.

c.f.: Help selecting interface for optane - #2 by LiKenun

My CPU-connected PCIe slots are 5.0, and my chipset-connected PCIe slots are 4.0. All the devices (except for the SAMSUNG 780 QVO) are PCIe 3.0.

It means you can connect either an NVMe M.2 stick or an SATA M.2 stick to it.