£196.47 is ~$250 US. That is quite a lot of monies to be spending on a motherboard, especially if you really just need more sata ports.
The iGPU should be fine for Plex and media streaming, so the 16-lane PCI-E slot on an ITX board could be repurposed with an expansion slot with more sata ports. There are cheaper ITX boards available that could work with that configuration.
Do you need it to be in an ITX form factor? With microATX, you would not need either an expensive board or an add-in.
Do you already have a case in mind? If you just want it to be very small, the add-in card would work and there are plenty of small micro-atx cases.
As more drives are added RaidZ2 offers more capacity, in exchange for performance, in a vdev compared to Raid 10. At very low drive counts, like 3-4, RaidZ2 offers both low performance and low capacity. If you are sure about a 4-drive configuration, I would recommend Raid 10 instead. That would offer 50% the space and excellent performance. Or if you want more space than that, take the performance hit and use RaidZ1, although that will necessarily reduce redundancy by 1 disk.